Please use this identifier to cite or link to this item: http://dspace.hebron.edu:80/xmlui/handle/123456789/1111
Title: Grafting of Nitrogen-containing Monomers onto Poly(ethylene-alt- tetrafluoroethylene) Films by Bulk Polymerization for Proton Exchange Membranes.
Authors: Takrori, F.
Keywords: Radiation induced grafting
Bulk polymerization
N-containing monomers
ETFE films
Issue Date: 12-Nov-2015
Publisher: Springer Netherlands
Citation: 4
Abstract: Bulk polymerization is suggested as an alternative to solution polymerization to graft N-containing monomers onto poly(ethylene-alt-tetrafluoroethylene) films to produce highly conductive membranes. Among the tested monomers, 4-vinyl pyridine was found as the most reactive monomer giving grafting levels (%GL)[120 % compared with %GL\45 % previously reported under similar conditions. Doping grafted films with H3PO4 converted them to membranes with enhanced water swellability but their conductivity values were at the same order of magnitude of membranes prepared by solution polymerization. These results demonstrate the importance of having both high grafting levels and homogeneous distribution of grafting throughout the base polymer.
URI: http://dspace.hebron.edu:80/xmlui/handle/123456789/1111
ISSN: 0236-5731
Appears in Collections:Journals

Files in This Item:
File Description SizeFormat 
file 3.pdf659.52 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.